Sharp JX-9400 Informations techniques Page 141

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Wal et al., 1998). These lists can inspire a selection of compounds to include in
the mix. However, the total number of compounds should not be too large in
order to keep the analysis at a practical level. Therefore, the list in Table 6.2,
which includes most significant VOCs for several classes of organic
compounds, was found suitable after careful selection.
It should be noted that acetic and butyric acids were chosen in a first step,
but eliminated after the initial experiments for two reasons. First, because they
are poorly selected by the columns used in the gas chromatograph, and second,
because butyric acid has an awful smell.
Example of application
Experiments were performed on three small to medium air handling units,
ventilating an auditorium and a laboratory at the EPFL,
1
and a building at
the EMPA.
2
The character istics of these units, measured using tracer gas
dilution technique, are summarized in Table 6.3.
Both EPFL units are equipped with a rotating heat exchanger, whose wheel
has a diameter of 785 mm, is 200 mm thick and rotates at 11 rpm. It is made of
thin aluminium sheet, sinusoidally corrugated with a wav elength of 4.2 mm and
peak-to-peak amplitude of 1.9 mm. A flat foil is placed between corrugated foils
(see Figure 6.12). The aluminium sheets are treated to have a hygroscopic
surface (see Figure 6. 13)
The purging sector is a rectangle 100 mm high and 40 mm thic k. The
purging sector was correctly used in the laboratory unit. The auditorium
Table 6.2 List of VOCs used for contaminant transfer experiments
Class
Compound
(current names) Formula Sources
Boiling
point
[
o
C]
Alkanes n-decane C
10
H
22
Paints and associated
supplies
174
Alcohols n-butanol CH
3
(CH
2
)
3
OH Adhesives 117
1-hexanol CH
3
(CH
2
)
5
OH Solvent 158
phenol C
6
H
5
OH 182
Haloalcanes 1,6-dichlorohexane Cl(CH
2
)
6
Cl Solvent, adhesives 203
Aldehydes hexanal (caproaldehyde) CH
3
(CH
2
)
4
CHO Paper, paints 128
benzaldehyde C
6
H
5
CHO Adhesives 179
Cyclic and
aromatic
4-isopropenyl 1-methyl
cyclohexene (limonene)
C
10
H
16
Perfumed waxes and
cleaners
177
hydrocarbons 1,3-dimethylbenzene
(m-xylene)
1,3-(CH
3
)
2
C
6
H
4
Solvent, fuel 139
1,3,5-trimethylbenzene
(mesitylene)
1,3,5-(CH
3
)
3
C
6
H
3
Solvent, fuel 165
Ethers dipropylether CH
3
(CH
2
)
2
O(CH
2
)
2
CH
3
Paints and associated
supplies
91
120 Ventilation and Airflow in Buildings
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